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Alli is a weight loss supplement that you can buy online at Walgreens.com. You can buy either the Weight Loss Aid capsules or the Alli Orlistat starter pack as well as refills for both. If you choose to stop taking Alli or any other weight loss supplement like it, the producers of the drug recommend that you continue to adhere to a physical activity and diet routine. These two aspects are essential to any weight loss program.